Tap Water Safety: Chlorine & Chloramines
Tap water safety for aquariums: Why chlorine and chloramines are deadly to fish and filter bacteria, and how to properly treat water for safe, stress-free changes.
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Tap Water: Friend or Foe?
To us, tap water is clean and safe. To a fish, it is a chemical bath that burns gills and destroys slime coats. This is because municipalities add disinfectants to kill bacteria in the pipes.
OriginUnknown
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ChemistryInert
The Two Disinfectants
1. Chlorine ($Cl_2$)
- What is it?: A gas dissolved in water. It is volatile and evaporates naturally.
- Removal:
- Aging: Letting water sit in a bucket for 24 hours (with an air stone) will gas off 99% of Chlorine.
- Chemicals: Standard dechlorinators work instantly.
2. Chloramine ($NH_2Cl$)
- What is it?: A combination of Chlorine + Ammonia. It is stable and does not evaporate.
- Removal:
- Aging: Does NOT work. You can age it for weeks, and it will still be there.
- Chemicals: You need a dechlorinator specifically designed to break the Chlorine-Ammonia bond (like Prime or Safe).
Why This Matters
If you add untreated tap water to your tank:
- Biological Genocide: Chlorine kills bacteria. It will wipe out your beneficial filter bacteria, crashing your cycle.
- Gill Damage: It chemically burns the delicate gill filaments of fish, causing suffocation.
Water Change Best Practices
- Treat the New Water: Add conditioner to the bucket before pouring it into the tank.
- Treat the Whole Tank: If you use a hose (Python system) to fill directly from the tap, dose enough conditioner for the entire tank volume, not just the water you added.
- Temperature Match: Ensure the new water is within 2°F (-17°C) of the tank water to prevent shock (and Ich).
RO/DI Water
Reverse Osmosis / Deionized water is 100% pure $H_2O$. It has:
- 0 ppm Chlorine
- 0 ppm Ammonia
- 0 KH / 0 GH
Warning: You cannot use pure RO water alone! It has no minerals (GH) or buffer (KH). You must "remineralize" it with products like Equilibrium or mix it with tap water.